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Sains Malaysiana 45(10)(2016): 1461–1468
Biodiesel from Thevetia peruviana Seed
Oil with Dimethyl Carbonate Using
as an Active Catalyst Potassium-Methoxide (Biodiesel daripada
Minyak Biji
Thevetia peruviana dengan Dimetil Karbonat Digunakan sebagai
Pemangkin Aktif
Kalium-Metoksid) BALAJI M.
PANCHAL1*,
SANJAY
A.
DESHMUKH2
& MUNISH R.
SHARMA2 1Department of Biochemistry,
Dr. Babasaheb Ambedkar
Marathawada University, Aurangabad,
Maharashtra 431004, India 2Nurture Earth Research
and Development Pvt. Ltd., MIT, Beed Bypass Road, Aurangabad 431028,
India Diserahkan: 20 Mei 2015/Diterima: 18 Februari 2016 ABSTRACT The transesterification of
Thevetia peruviana seed
oil with dimethyl carbonate (DMC) for preparing biodiesel has
been studied using as an active catalyst potassium-methoxide (KOCH3).
The effects of reaction conditions: Molar ratio
of dimethyl carbonate to Thevetia peruviana seed oil, catalyst concentration, reaction time
and agitation speed on dimethyl esters (DMC-Tp-BioDs) yield were investigated.
The highest DMC-Tp-BioDs
yield could reach 97.1% at refluxing temperature for 90 min with
molar ratio of DMC-to-oil
5:1 and 2.0% w/w KOCH3 (based
on oil weight). The fuel properties of the produced DMC-Tp-BioDs were compared with the
ASTM
D6751-02 biodiesel standard. Keywords: Biodiesel; dimethyl
carbonate; oil extraction; optimization conditions; potassium
methoxide; Thevetia peruviana seed oil ABSTRAK Pengesteran trans daripada minyak
biji Thevetia peruviana dengan dimetil karbonat (DMC)
untuk menyediakan biodiesel telah dikaji digunakan
sebagai suatu
pemangkin aktif kalium-metoksid (KOCH3).
Kesan tindak
balas keadaan: hasil nisbah molar dimetil karbonat minyak biji Thevetia peruviana, pemangkin kepekatan, masa reaksi dan kelajuan
pergerakan dimetil
ester (DMC-Tp-BioDs) dikaji.
Kadar hasil tertinggi
DMC-Tp-BioDs boleh
mencapai 97.1% pada
perefluksan suhu untuk 90 min dengan nisbah molar DMC-kepada-minyak 5:1 dan 2.0% w/w KOCH3 (berdasarkan berat minyak). Sifat bahan api
yang dihasilkan DMC-Tp-BioDs dibandingkan
dengan piawaian
ASTM
D6751-02 biodiesel. Kata kunci: Biodiesel; kalium metoksid; karbonat dimetil; keadaan pengoptimuman; minyak biji Thevetia peruviana;
pengekstrakan minyak RUJUKAN Abbaszaadeh,
A., Ghobadian, B., Omidkhah,
M.R. & Najafi, G. 2012. Current biodiesel
production technologies: A comparative review. Energy Conversion
and Management 63: 138-148. Antony,
S.R., Robinson, D.S. & Lindon, R.L.C. 2011. Biodiesel production from Jatropha oil and its characterization.
Research Journal of Chemical Science 1(1): 81-87. Atabani,
A.E., Silitonga, A.S., Ong, H.C., Mahlia,
T.M.I., Masjuki, H.H., Badruddin,
I.A. & Fayaz, H. 2013. Non-edible vegetable
oils: A critical evaluation of oil extraction, fatty acid compositions,
biodiesel production, characteristics, engine performance and
emissions production. Renewable and Sustainable Energy Reviews
18: 211-245. Basumatary, S. 2015. Yellow
oleander (Thevetia peruviana) seed oil biodiesel as an alternative and renewable
fuel for diesel engines: A review. International Journal of
ChemTech Research 6(7): 2823-2840. Basumatary,
S. & Deka, D.C. 2014. Transesterification
of yellow oleander (Thevetia
peruviana) seed oil to fatty acid
methyl esters (biodiesel) using a heterogeneous catalyst derived
from rhizome of Musa balbisiana Colla. International
Journal ChemTech Research 6(4):
2377-2384. Bobade,
S.N. & Khyade, V.B. 2012. Preparation of methyl ester (Biodiesel) from karanja
(Pongamia pinnata)
oil. Research Journal of Chemical Sciences 2(8):
43-50. Canakci,
M. & Gerpen, V. 1999. Biodiesel production via acid catalysis. Transactions of
American Society of Agricultural Engineers 42(5): 1203-1210.
Demirbas,
A. 2009.
Progress and recent trends in biodiesel fuels.
Energy Conversion and Management 50(1): 14-34. Dennis,
Y.C., Leung, X.W. & Leung, M.K.H. 2010. A review on biodiesel production using catalyzed transesterification.
Applied Energy 87: 1083-1095.
Dhoot,
S.B., Jaju, D.R., Deshmukh,
S.A., Panchal, B.M. & Sharma, M.R. 2011. Extraction of Thevetia peruviana seed oil and optimization of biodiesel production
using alkali-catalyzed methanolysis.
Journal of Alternate Energy Sources and Technologies 2(2):
8-16. Edward,
N.O. & Peggy, A.O. 2013. Optimization of biodiesel
production from nonedible seeds of Delonix
regia (Gul Mohr). International
Journal of Bioresource Technology 1(1):
01-08. Encinar,
J.M., Juan, F., Gonzalez, J.F. & Rodriguez-Reinares,
A. 2007.
Ethanolysis of used frying oils: Biodiesel
preparation and characterization. Fuel Processing Technology
88(5): 513-522. Encinar,
J.M., Gonzalez, J.F. & Rodriguez-Reinares,
A. 2005.
Biodiesel from used frying oil. Variables
affecting the yields and characteristics of the biodiesel.
Journal of Industrial and Engineering Chemistry Research 44(15):
5491-5499. Fabbri, D., Bevoni, V., Notari, M. & Rivetti, F. 2007. Properties of a potential biofuelobtained from soybean oil by transmethylation
with dimethyl carbonate. Fuel 86: 690-697. Fernando,
S., Karra, P., Hernandez, R. & Jha, S.K. 2007. Effect of incompletely
converted soybean oil on biodiesel quality. Energy 32(5):
844-851. Freedman,
B., Butterfield, R.O. & Pryde, E.H.
1986. Transesterification kinetics of soybean oil. Journal of
American Chemist Society 63: 1375-1380. Fukuda,
H., Kondo, A. & Noda, H. 2001. Biodiesel fuel production
by transesterification of oils. Journal of Bioscience
and Bioengineering 92(5): 405-416. Gupta, A., Sharma,
S.K. & Pal Toor, A. 2007. Production of biodiesel from waste soybean oil. Journal
of Petrotech Society 4(1): 40-45.
Ibiyemi,
S.A., Bako, S.S., Fadipe, V.O. &
Akinremi, O.O. 2002. Variation in
oil composition of Thevetia
perviana fruit seeds. Journal of Applied Sciences
and Environmental Management 6(2): 61-65. Knothe,
G. & Steidley, K.R. 2005. Kinematic viscosity of biodiesel fuel components and related compounds.
Influence of compound structure and comparison to petro diesel
fuel components. Fuel 84: 1059-1065. Ma,
F. & Hanna, M.A. 1999. Biodiesel production: A review. Bioresource Technology 70: 1-15. Martini,
N. & Shell, J.S. 1998. Plant Oils as Fuels-Present
State of Science and Future Development. Berlin:
Spinger. p. 276.
Meher,
L.C., Dharmagadda, V.S.S. & Naik,
S.N. 2006.
Optimization of alkali-catalyzed transesterification
of Pongamia pinnata oil
for production of biodiesel. Bioresource
Technology 97: 1392-1397. Mohammed,
M.L. & Hamza, Z.U. 2008. Physicochemical properties
of oil extracts from Sesamum
indicum L. seeds grown
in Jigawa state - Nigeria. Journal
of Applied Sciences and Environmental Management 12(2): 99-101.
Nakpong, P. & Wootthikanokkhan, S. 2010. Optimization
of biodiesel production from Jatropha curcas
L. oil via alkali-catalyzed methanolysis.
Journal of Sustainable Energy and Environment 1: 105-109.
Neelam,
R. & Anil, K. 2014. Pharmacological importance of Thevetia peruviana.
International Journal of Pharmaceutical and Chemical Science 3(1):
260-263. Panchal,
B.M., Dhoot, S.B., Deshmukh, S.A., Sharma,
M.R. & Kachole, M.S. 2013. Production of DMC-BioD from Pongamia pinnata seed
oil using dimethyl carbonate. Fuel 109: 201-205.
Pasqualinoa,
J.C., Montanea, D. & Salvado,
J. 2006.
Synergic effects of biodiesel in the biodegradability
of fossil-derived fuels. Biomass and Bioenergy 30:
874-879. Raghunath,
D.P., Funde, P.E., Joshi, S.S. &
Pingale, S.S. 2008. Synthesis and
characterization of fatty acid methyl ester by in-situ transesterification
in Capparis deciduas
seed. Leonardo Electronic Journal of Practices Technologies
13: 12-18. Refaat, A.A., Attia,
N.K., Sibak, H.A., El Sheltawy,
S.T. & El Diwani, G.I. 2008. Production
optimization and quality assessment of biodiesel from waste vegetable
oil. International Journal of Environmental Science
and Technology 5(1): 75-82. Singh, S.P. & Singh,
D. 2010. Biodiesel production through the use of different sources and
characterization of oils and their esters as the substitute of
diesel: A review. Renewable and Sustainable Energy Reviews
14: 200-216. Tewtrakul,
S., Nakamora, N., Hattori, M., Fugiwara,
T. & Suparita, T. 2002. Flavonone and flavonol glycosides
from leaves of Thevetia peruviana
and their HIV-1 reverse stranscriptase
and HIV-1, integrase inhibitory activities. Chemical and Pharmaceutical Bulletin 50: 630-635. Tomasevic,
A.V. & Siler-Marinkovic, S.S. 2003. Methanolysis of
used frying oil. Fuel Processing Technology 81(1):
1-6. Tundo,
P. & Selva, M. 2002. The chemistry of dimethyl carbonate. Accounts of Chemical
Research 35: 706-716. Ugheoke,
B.I., Patrick, D.O., Kefas, H.M. &
Onche, E.O. 2007. Determination of optimal
catalyst concentration for maximum biodiesel yield from tigernut (Cyperus esculentus) oil. Leonardo Journal of Science
10: 131-136. Umer,
R., Farooq, A., Bryan, R.M. & Samia,
A. 2008. Production of
sunflower oil methyl esters by optimized alkali-catalyzed methanolysis.
Biomass and Bioenergy 32: 1202-1205. Usman,
L.A., Oluwaniyi, O.O., Ibiyemi,
S.A., Muhammad, N.O. & Ameen, O. 2009. The potential of Oleander (Thevetia peruviana)
in African agricultural and industrial development: A case study
of Nigeria. Journal of Applied Biosciences 24: 1477-1487.
Venkanna, B.K. & Venkataramana Reddy, C. 2009. Biodiesel production and optimization
from Calophyllum inophyllum linn oil (honne oil) - A three stage method. Bioresource
Technology 100: 5122-5125. Wang,
M., Wang, H., Zhao, N., Wei, W. & Sun, Y. 2006. Synthesis of dimethyl carbonate from urea and methanol over solid
base catalysts. Catalysis Communications 7: 6-10.
Zhang, L., Sheng,
B., Xin, Z., Liu, Q. & Sun, S. 2010. Kinetics
of transesterification of palm oil and dimethyl carbonate for
biodiesel production at the catalysis of heterogeneous base catalyst.
Bioresource Technology 101(21):
8144-8150. *Pengarang untuk surat-menyurat; email: panchalbalaji@yahoo.co.in
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