Sains Malaysiana 46(4)(2017): 615–621

http://dx.doi.org/10.17576/jsm-2017-4604-14

 

Rapid Extraction of Bisphenol A by Dispersive Liquid-Liquid Microextraction based on Solidification of Floating Organic

(Pengekstrakan Pantas Bisfenol A dengan Pengekstrakan Mikro Cecair-Cecair Serakan berdasarkan Pemejalan Organik Terapung)

SAW HONG LOH1,2*, SHAN TEIK ONG1, MEE LIN NGU1 & MARINAH MOHD ARIFFIN1

 

1School of Marine and Environmental Sciences, Universiti Malaysia Terengganu

21030 Kuala Terengganu, Terengganu Darul Iman, Malaysia

 

2Institute of Marine Biotechnology, Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu Darul Iman, Malaysia

 

Diserahkan: 16 Februari 2016/Diterima: 21 September 2016

 

ABSTRACT

Bisphenol A is an endocrine disruptor with widespread applications, especially in the production of polycarbonate and epoxy resins. Dispersive liquid-liquid microextraction based on solidification of floating organic technique has been developed for the extraction of bisphenol A from water and soft drink. The 1-undecanol has been applied as the extraction solvent because of its low density and melting point and high affinity to the analyte. The technique offered rapid and simple analysis as the 1-undecanol was homogeneously dispersed in the sample solution to speed the extraction and the collection of extraction solvent was simplified by centrifugation, cooling and melting steps.

 

Keywords: Bisphenol A; dispersive liquid-liquid microextraction based on solidification of floating organic; high performance liquid chromatography-fluorescence detection; water

 

ABSTRAK

Bisfenol A ialah suatu pengganggu endokrin yang mempunyai aplikasi meluas, khususnya dalam pengeluaran polikarbonat dan resin epoksi. Teknik pengekstrakan mikro cecair-cecair serakan berdasarkan pemejalan organik terapung telah dibangunkan untuk mengekstrak bisfenol A daripada air dan minuman ringan. 1-undekanol telah digunakan sebagai pelarut pengekstrakan disebabkan ketumpatan dan takat leburnya yang rendah dan tarikannya yang kuat terhadap analit. Teknik ini menawarkan analisis yang pantas dan senang kerana 1-undekanol menyerak dengan homogen di dalam larutan sampel untuk mempercepatkan pengekstrakan dan pengumpulan pelarut pengekstrakan telah dipermudahkan melalui langkah pengemparan, penyejukan dan peleburan.

 

Kata kunci: Air; bisfenol A; kromatografi cecair prestasi tinggi-pengesanan pendarfluor; pengekstrakan mikro cecair-cecair serakan berdasarkan pemejalan organik terapung

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*Pengarang untuk surat-menyurat; email: lohsh@umt.edu.my

 

 

 

 

 

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