Sains Malaysiana 48(5)(2019): 1025–1033

http://dx.doi.org/10.17576/jsm-2019-4805-11

 

Immobilization of Choline Chloride: Urea onto Mesoporous Silica for Carbon Dioxide Capture

(Pemegunan Kolina Klorida: Urea ke atas Silika Mesoliang untuk Penangkapan Karbon Dioksida)

 

ZAITUN GHAZALI1,2, NUR HASYAREEDA HASSAN1,2, MOHD AMBAR YARMO1,3, TEH LEE PENG1,3 & RIZAFIZAH OTHAMAN1,2*

 

1School of Chemical Sciences and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia

 

2Polymer Research Center, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia

 

3Catalyst Research Group, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan, Malaysia

 

Diserahkan: 7 Februari 2019/Diterima: 28 Mac 2019

 

ABSTRACT

A green composite adsorbent based on mesoporous silica-gel (SG) and deep eutectic solvent (DES) mixture of choline chloride-urea (ChCl:U) was synthesized as an alternative for carbon dioxide (CO2) adsorption. The composite adsorbent was prepared by wet impregnation technique with various ChCl:U (mole ratio 1:2) content in SG at 5-15% (w/w). Fourier transform infrared attenuated total reflectance (ATR-FTIR) results showed successful impregnation of ChCl:U into SG with the presence of C=O carbonyl amide group stretching, N-H scissoring bending, CH2 bending and C-N stretching peaks. Thermal degradation of the adsorbent started with urea at 130°C followed by ChCl at 300°C. Meanwhile, nitrogen physisorption demonstrated a decrease in specific surface areas of the sorbents with increasing ChCl:U weight percentage due to the blockage of micropores by ChCl:U. The optimum CO2 adsorption capacity of 22.3 mg/g was achieved by 10% ChCl:U/SG200, which was higher than the immobilised SG200, hence making it relevant to become a green and economical adsorbent for CO2 capture.

 

Keywords: Adsorption; carbon capture; choline chloride; deep eutectic solvent; silica gel; urea

 

ABSTRAK

Penjerap komposit hijau berasaskan gel silika mesoliang (SG) dan pelarut eutektik dalam (DES) kolona klorida-urea (ChCl:U) disintesis untuk penjerapan karbon dioksida (CO2). Penjerap komposit telah disediakan dengan teknik penjejalan basah dengan muatan 5-15% (b/b) ChCl:U (nisbah mol 1:2). Spektrum inframerah transformasi Fourier-pantulan penuh kecil (ATR-FTIR) membuktikan bahawa ChCl:U telah berjaya dijejalkan ke atas SG dengan kehadiran puncak regangan kumpulan karbonil amida C=O , bengkokan N-H , bengkokan CH2 dan regangan C-N. Suhu degradasi penjerap bermula dengan urea pada 130°C diikuti oleh ChCl pada 300°C. Analisis penjerapan fizikal nitrogen menunjukkan penurunan luas permukaan dengan peningkatan peratus berat ChCl:U disebabkan mikroliang yang dilitupi oleh ChCl:U. Kapasiti penjerapan CO2 yang optimum (22.3 mg/g) tercapai dengan menggunakan 10% ChCl:U/SG200 dengan kapasiti penjerapannya lebih tinggi berbanding SG200 tanpa pemegunan,. Ini menjadikannya penjerap hijau yang ekonomi untuk penangkapan CO2.

 

Kata kunci: Gel silika; kolina klorida; pelarut eutektik dalam; penangkapan karbon; penjerapan; urea

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*Pengarang untuk surat-menyurat; email: rizafizah@ukm.edu.my

 

 

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