The Malaysian Journal of Analytical Sciences Vol 13 No 2 (2009): 165 – 169
STABILITY OF CURCUMIN IN TURMERIC OLEORESIN-
β-CYCLODEXTRIN INCLUSION COMPLEX DURING STORAGE
(KESTABILAN
KURKUMIN DI DALAM KOMPLEKS RANGKUMAN OLEORESIN- β-
SIKLODEKSTRIN SEMASA PENYIMPANAN)
Zaibunnisa,
A.H.1, Norashikin, S.1, Mamot, S.2 and Osman,
H.2
1Faculty
of Applied Sciences, Universiti Teknologi MARA
40450 Shah Alam,
2Faculty
of Science and Technology, Universiti Kebangsaan
43600 Bangi,
Abstract
To improve the stability of curcumin in turmeric
rhizome (Curcuma domestica) oleoresin
during storage, complexation with β-cyclodextrin was studied. Pressurised
liquid extraction (PLE) is a fast method to extract high quality turmeric
rhizome oleoresin. Extraction conditions
was optimised based on maximum major volatile compounds (1,8-cineol, tumerone +
ar-tumerone, α-zingeberene, β-zingeberene and α-phellandrene). Turmeric oleoresin
exhibit sensitivity to light, heat, oxygen and have short storage lives.
Therefore, oleoresin obtained was encapsulated with β-cyclodextrin (BCD)
using kneading method. The stability of
curcumin in inclusion complex was monitored for 64 days with exposure to heat
and light. The shelf-life of the product was estimated based on half life t1/2
(day) and activation energy, E (kJ/mol). Shelf life of turmeric oleoresin
inclusion complex, stored at 5oC in dark containers can be extended
to 154 days.
Keywords: curcumin, light, storage, kinetic study, half life and
activation energy.
References
1. Bong, P. 2000. Spectral and photophysical
behaviour of curcumin and curcuminoids. Bulletin
Korean Chemical Society 21(1): 81-86.
2. Showbagya,
H.B., Smitha, S. Sampathu, S.R., Krishnamurthy, N. & Battacharya, S. 2005.
Stability of water-soluble turmeric colorant in an extruded food product during
storage. Journal of Food Engineering 67
(3): 367-371.
3. Shaik, J., Bhosale, R. & Singhal, R. 2006. Microencapsulation
of black pepper oleoresin. Food Chemistry
94: 105-110
4. Maing, Y.
& Miller, I. 1981. Curcumin-metal colour complexes and process for
preparing them. European Pattern
Application. EP 25 637 A1.
5. Szente, L., Mikuni, K., Hashimoto, H. &
Szejtli, J. 1998. Stabilization and Solubilization of Lipophilic Natural
Colorants with Cyclodextrins. Journal of
Inclusion Phenomena and Molecular Recognition in Chemistry 32: 81–89.
6. Zhang, A., Liu, W., Wang, L. & Wen, Y.
2005. Characterization of
inclusion complexation between fenoxaprop-p-ethyl and cyclodextrin. Journal of Agricultural and Food Chemistry 53(18):
7193-7197.
7. ASTA 1985. Official Methods American Spice
Trade Association. Engelwood Cliff, New Jersey.
8. Van Boekel, M.A.J.S. 2008. Kinetic modelling of food
quality. Comprehensive Reviews in Food
Science and Food Safety 7: 144-158.