The Malaysian Journal of Analytical Sciences Vol 12 No 3 (2008): 536 – 541

 

 

PALM-BASED LAURYL ALCOHOL ETHOXYLATE BEHAVIOURAL STUDY AND RECOMMENDATIONS IN PERSONAL CARE APPLICATIONS

 

Lim Hong Ngee1, Anuar Kassim1, Atan Sharif1, Dzulkefly Kuang1, Ambar Yarmo2, Zarina Edris2,

Rosnah Ismail3, and Huang Nay Ming4

 

1Chemistry Department, Faculty of Science, Universiti Putra Malaysia,

43400 UPM Serdang, Selangor Darul Ehsan, Malaysia.

2School of Chemical Sciences and Food Technology, Faculty of Science and Tachnology,Universiti Kebangsaan Malaysia,

43000 Bandar Baru Bangi, Selangor Darul Ehsan, Malaysia.

3AOTD MPOB, Lot 9 & 11, Jalan P10/14, Seksyen 10, 43650 Bandar Baru Bangi, Selangor Darul Ehsan, Malaysia.

4School of Applied Physics, Faculty of Science and Technology,Universiti Kebangsaan Malaysia,

43000 Bandar Baru Bangi, Selangor Darul Ehsan, Malaysia.

 

Abstract

Palm-based lauryl alcohol ethoxylate was synthesized with 6 moles of ethylene oxide using an ethoxylation reactor. The 6 moles of ethylene oxide chain length was approximately the same length as the palm-based lauryl alcohol. The synthesized lauryl alcohol ethoxylate consisted of an average of 6 moles of ethylene oxide and was labeled as C12EO6. The molecular structure of lauryl alcohol ethoxylate was determined by Fourier Transformed Infrared Spectroscopy (FTIR). The ternary phase diagrams for olive or olein oil/water/C12E6   systems were investigated at 25oC. The important features of the ternary phase diagrams are the emulsion and the concentrated  emulsion  phases. Optical microscope, particle size analyser and rheometer were used to characterize the  different compositions of emulsions. Different consistencies of emulsions were recommended for the personal care applications.

 

Keywords: palm-based lauryl alcohol ethoxylate, ethoxylation reactor, ternary phasediagram, emulsion, concentrated emulsion

 

References

1.     Sjoblom, J. (1996). Emulsions and Emulsion  Stability. Surfactant Science Series Vol. 61. New York: Marcel Dekker.

2.     Mishchuk, N. A., Sanfeld, A., Steinchen, A. (2004). Interparticle interactions in concentrate water-oil emulsions. Advances in Colloid and Interface Science, 112, 129-157.

3.     Kizling, J. and Kronberg, B. (2001). On the formation of concentrated stable W/O emulsions. Advances in Colloid and Interface Sciences, 89-90, 395-399.

4.     Williams,  J.  M.  (1991).  High  internal  phase  water-in-oil  emulsions:  Influence  of  surfactants  and cosurfactants on emulsion stability and foam quality or gel-emulsions. Langmuir, 7, 1370-1377.

5.     Ravey, J. C., Stébé, M. J., Sauvage, S. (1994). Water  in fluorocarbon  gel emulsions:  Structures and rheology Colloids and Surfaces A, Physicochemical and Engineering Aspects, 91, 237-257.

6.     Kizling, J., Kronberg, B., Eriksson, J. C. (2006). On the formation and stability of high internal phase O/W emulsions. Advances in Colloid and Interface Science, 123-126, 295-302.

7.     Latreille, B. and Paquin, P. (1990). Evaluation of emulsion stability by centrifugation with conductivity measurements. Journal of Food Science, 55, 1666-1668.

8.     Ribeiro, H. M., Morais, J. A., Eccleston, G. M. (2004). Structure and rheology of semisolid o/w creams containing  cetyl  alcohol/non-ionic  surfactant  mixed  emulsifier  and  different  polymers.  International Journal of Cosmetic Science, 26, 47-59.

9.     Terrisse, I., Seiller, M., Rabaron, A., Gossiord, J. L. (1993). Rheology: How to characterize and to predict the evolution of W/O/W multiple emulsions. International Journal of Cosmetic Science, 15, 53-62.

 




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