Sains Malaysiana 52(1)(2023): 261-269

http://doi.org/10.17576/jsm-2023-5201-21

 

Optical Properties of Reduced Graphene Oxide-Coated Tellurite Glass Doped at Different Erbium Composition

(Sifat Optik Kaca Telurit Bersalut Graphene Oksida Terkurang Didop pada Komposisi Erbium Berbeza)

 

AZLINA YAHYA, MUHAMMAD NOORAZLAN ABD AZIS* & SURIANI ABU BAKAR

 

Physics Department, Faculty of Science and Mathematics, Universiti Pendidikan Sultan Idris, 35900 Tanjung Malim, Perak Darul Ridzuan, Malaysia

 

Received: 31 May 2022/Accepted: 11 October 2022

 

Abstract

Graphene-based nanomaterials have significant potential to be used as coating materials for glass performance. In this work, reduced graphene oxide (rGO)-coated tellurite glass was synthesized via melt-quenching and low-cost spray coating techniques for improving the optical properties in the glassy matrix. The structural properties investigated using X-Ray Diffraction (XRD) confirmed the structural arrangement of an amorphous nature phase meanwhile, Scanning Electron Microscopy (SEM) analysis proved the morphological structure images of rGO onto the tellurite glass surface. The refractive index value of rGO-coated glass was found higher in the range of 2.402 - 2.775 due to the graphene-based effects. The optical bandgap energy value of rGO-coated glass was improved from 1.913 - 2.980 eV which correlated to the changes in rGO absorption characteristics. The Urbach energy showed a high number of defects in absorption with the presence of rGO structures. By virtue of improved optical properties, the rGO-coated glass may be beneficial to be used as a glass coating material for high optical performance of fiber optics.

 

Keywords: Erbium nanoparticles; rGO; tellurite glass

 

Abstrak

Bahan nano berasaskan grafin mempunyai potensi ketara untuk digunakan sebagai bahan salutan untuk prestasi kaca. Dalam kajian ini, kaca tellurit disalut grafin oksida terkurang (rGO) telah disintesis melalui teknik lebur lindap dan salutan semburan kos rendah untuk meningkatkan sifat optik dalam kaca matriks. Sifat struktur yang dijalankan menggunakan pembelauan sinar-X (XRD) mengesahkan susunan struktur fasa sifat amorfus manakala, analisis mikroskop pengimbasan elektron (SEM) membuktikan imej struktur morfologi rGO pada permukaan kaca tellurit. Nilai indeks biasan kaca disaluti rGO didapati lebih tinggi dalam julat 2.402 - 2.775 disebabkan oleh kesan berasaskan grafin. Nilai tenaga jurang jalur optik kaca disaluti rGO telah meningkat dari 1.913 - 2.980 eV yang dikaitkan dengan perubahan dalam ciri penyerapan rGO. Tenaga Urbach menunjukkan bilangan kekurangan yang tinggi dalam penyerapan dengan kehadiran struktur rGO. Berdasarkan sifat optik yang dipertingkatkan, kaca disaluti rGO bermanfaat untuk digunakan sebagai bahan salutan kaca untuk prestasi tinggi gentian optik.

 

Kata kunci: Kaca telurit; nanozarah erbium; rGO

 

REFERENCES

Abozied, A.M., Mostafa, A.M., Abouelsayed, A., Hassan, A.F., Ramadan, A.A., Al-Ashkar, E.A. & Anis, B. 2021. Preparation, characterization, and nonlinear optical properties of graphene oxide thin film doped with low chirality metallic SWCNTs. Journal of Materials Research and Technology 12: 1461-1472.

Al-Gaashani, R., Najjar, A., Zakaria, Y., Mansour, S. & Atieh, M.A. 2019. XPS and structural studies of high quality graphene oxide and reduced graphene oxide prepared by different chemical oxidation methods. Ceramics International 45: 14439-14448.

Amjad, R.J., Sahar, M.R., Ghoshal, S.K., Dousti, M.R. & Arifin, R. 2013. Synthesis and characterization of Dy3+ doped zin –lead-phosphate glass. Optical Materials 35: 1103-1108.

Aradhana, D.M., Dissanayake, S., Cifuentes, M.P. & Humphrey, M.G. 2018. Optical limiting properties of (reduced) graphene oxide covalently functionalized by coordination complexes. Coordination Chemistry Reviews 375: 489-513.

Azlan, M.N., Halimah, M.K., Suriani, A.B., Azlina, Y., Umar, S.A. & El-Mallawany, R. 2019. Upconversion properties of erbium nanoparticles doped tellurite glasses for high efficient laser glass. Optics Communications 448: 82-88.

Azlan, M.N., Halimah, M.K., Shafinas, S.Z. & Daud, W.M. 2015. Electronic polarizability of zinc borotellurite glass system containing erbium nanoparticles. Materials Express 5(3): 211-218.

Bhuyan, M.S.A., Uddin, M.N., Islam, M.M., Bipasha, F.A. & Hossain, S.S. 2016. Synthesis of graphene. International Nano Letters 6(2): 65-83.

Bonavolontà, C., Vettoliere, A., Falco, G., Aramo, C., Rendina, I., Ruggiero, B., Silvestrini, P. & Valentino, M. 2021. Reduced graphene oxide on silicon-based structure as novel broadband photodetector. Scientific Reports 11: 13015.

Cao, Y., Chai, D., Luo, Z., Jiang, M., Xu, W., Xiong, C., Li, S., Liu, H. & Fang, D. 2017. Lithium vanadate nanowires@reduced graphene oxide nanocomposites on titanium foil with super high capacities for lithium-ion batteries. Journal of Colloid and Interface Science 498: 210-216.

Dimitrov, V. & Sakka, S. 1996. Linear and nonlinear optical properties of simple oxides. II. Journal of Applied Physics 79(3): 1741-1745.

Effendy, N., Sidek, H.A.A., Halimah, M.K. & Zaid, M.H.M. 2021. Enhancement on thermal, elastic and optical properties of new formulation tellurite glasses: Influence of ZnO as a glass modifier. Materials Chemistry and Physics 273: 125156.

El-Diasty, F., Wahab, F.A.A. & Abdel-Baki, M. 2006. Optical band gap studies on lithium aluminum silicate glasses doped with Cr3+ ions. Journal of Applied Physics 100: 093511.

Gao, X., Ju, P., Liu, X., Chen, L., Ji, L., Li, H., Zhou, H. & Chen, J. 2019. Macro-tribological behaviors of four common graphenes. Industrial and Engineering Chemistry Research 58(14): 5464-5471.

Jiménez-Pérez, J.L., Gutiérrez-Fuentes, R., López-Gamboa, G. & Sánchez-Ramírez, J.F. 2018. Measurement of optical nonlinear refractive index response of graphene nanoparticles dispersed in an aqueous solution by Z scan technique. Optical Materials 84: 236-241.

Liu, D., Li, C., Xu, Y., Zhou, D., Wang, H., Sun, P. & Jiang, H. 2017. Near-infrared luminescent erbium complexes with 8-hydroxyquinoline-terminated hyperbranched polyester. Polymer 113: 274-282.

Marzouk, S.Y., Azooz, M.A. & El Batal, H.A. 2021. Judd-Ofelt analysis of spectroscopic measurements of Er3+ doped boro-zincate glasses. Journal of Molecular Structure 1243: 130925.

Mott, N.F., Davis, E.A. & Weiser, K. 1972. Electronic processes in non‐crystalline materials. Physics Today 25(12): 55.

Omidvar, A., RashidianVaziri, M.R. & Jaleh, B. 2018. Enhancing the nonlinear optical properties of graphene oxide by repairing with palladium nanoparticles. Physica E: Low-Dimensional Systems and Nanostructures 103: 239-245.

Said Mahraz, Z.A., Sahar, M.R., Ghoshal, S.K. & Reza Dousti, M. 2013. Concentration dependent luminescence quenching of Er3+-doped zinc boro-tellurite glass. Journal of Luminescence 144: 139-145.

Shakeri, M.S. & Rezvani, M. 2011. Optical band gap and spectroscopic study of lithium alumino silicate glass containing Y3+ ions. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 79: 1920-1925.

Sharma, N., Arif, M., Monga, S., Shkir, M., Mishra, Y.K. & Singh, A. 2020. Investigation of bandgap alteration in graphene oxide with different reduction routes. Applied Surface Science 513: 145396.

Sreeja, V.G. & Anila, E.I. 2019. Studies on the effect of reduced graphene oxide on nonlinear absorption and optical limiting properties of potassium doped zinc oxide thin film by Z - scan technique. Thin Solid Films 685: 161-167.

Sreeja, V.G., Vinitha, G., Reshmi, R., Anila, E.I. & Jayaraj, M.K. 2017. Effect of reduction time on third order optical nonlinearity of reduced graphene oxide. Optical Materials 66: 460-468.

Tiwari, H. & Dhondiyal, C.C. 2021. Physical and optical analysis of Sm3+ doped zinc phosphate glass. Materials Today: Proceedings 47(Part 8): 1682-1688.

Umar, S.A., Halimah, M.K., Chan, K.T. & Latif, A.A. 2017. Polarizability, optical basicity and electric susceptibility of Er3+ doped silicate borotellurite glasses. Journal of Non-Crystalline Solids 471: 101-109.

Wshah, A.A.A., Halimah, M.K., Alazoumi, S.H., Umar, S.A. & Ibrahim, G.G. 2021. Elastic properties of TeO2–ZnO–Ag2O doped with Nd2O3. Materials Chemistry and Physics 260: 124195.

Yusof, N.N., Ghoshal, S.K. & Azlan, M.N. 2017. Optical properties of titania nanoparticles embedded Er3+-doped tellurite glass: Judd-Ofelt analysis. Journal of Alloys and Compounds 724: 1083-1092.

Zhang, Y., Xia, L., Li, C., Ding, J., Li, J. & Zhou, Y. 2021a. Enhanced 2.7 µm mid-infrared emission in Er3+/Ho3+ co-doped tellurite glass. Optics and Laser Technology 138: 106913.

Zhang, Y., Xia, L., Shen, X., Li, J., Yang, G. & Zhou, Y. 2021b. Broadband mid-infrared emission in Dy3+/Er3+ co-doped tellurite glass. Journal of Luminescence 236: 118078.

 

*Corresponding author; email: azlanmn@fsmt.upsi.edu.my

 

 

 

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